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Actinium - Ac

CAS: 7440-34-8
Description: Silvery-white radioactive metal
Classification: Actinide
Date of Discovery: 1899
Discoverer: Andre Debierne
Name Origin: Greek aktinos, "beam or ray"

Atomic Number: 89
Number of Neutrons: 138
Atomic Mass: (227) amu
Melting Point: 1051 °C
Boiling Point: 3200 ± 300 °C (est.)
Density (293 K): 10.07 g/cm3 (calc.)
Atomic volume: 22.54 cm3/mol
Electrical resistivity:
Thermal conductivity: 0.12 W/cmK
Enthalpy of atomization: 301 kJ/mol (est)
Enthalpy of vaporization:
Enthalpy of fusion:
Specific heat capacity: 0.120 J/g/K
Energy levels: 2-8-18-32-18-9-2
Electron configuration: [Rn]6d17s2
Crystal Structure: Cubic surface centered
Atomic radius:
Covalent radius:
Oxidation States: +3
Electronegativity, Pauling: 1.1
Electron affinity:
First ionization energy: 5.17 eV
2nd ionization energy: 12.126 eV
3rd ionization energy:
Polarizability: 32.1 10-24cm3
Isotope Natural Abundance Atomic Mass Half-life Decay Mode Spin
207Ac Alpha Symbol0.02 s alpha symbol
208mAc Alpha Symbol25 ms alpha symbol
208Ac Alpha Symbol0.1 s alpha symbol
209Ac 209.0096 Alpha Symbol0.09 s alpha symbol
210Ac 210.0093 0.4 s alpha symbol
211Ac 211.0076 0.3 s alpha symbol
212Ac 212.0078 0.9 s alpha symbol
213Ac 213.0066 0.8 s alpha symbol (9/2-)
214Ac 214.0069 8.2 s alpha symbol (5+)
215Ac 215.0065 0.17 s alpha symbol (9/2-)
216mAc 0.33 ms alpha symbol (9-)
216Ac 216.00871 Alpha Symbol0.3 ms alpha symbol (1)
217mAc 0.7 µs alpha symbol
217Ac 217.00933 0.07 µs alpha symbol 9/2-
218Ac 218.01162 1.1 µs alpha symbol
219Ac 219.01241 0.012 ms alpha symbol (9/2-)
220Ac 220.0148 26 ms alpha symbol
221Ac 221.01558 52 ms alpha symbol
222mAc 63 s alpha symbol; EC; IT
222Ac 222.01782 5 s alpha symbol 1-
223Ac 223.01913 2.1 m alpha symbol; EC (5/2-)
224Ac 224.021708 2.7 h EC; alpha symbol 0-
225Ac 225.02322 10.0 d alpha symbol 3/2
226Ac 226.026089 1.224 d EC; Beta Symbol-; alpha symbol (1-)
227Ac 227.027747 21.77 y Beta Symbol-; alpha symbol (3/2-)
228Ac 228.031014 6.15 h Beta Symbol- (3+)
229Ac 229.03293 1.04 h Beta Symbol- (3/2+)
230Ac 230.0360 2.03 m Beta Symbol- 1+
231Ac 231.0386 7.5 m Beta Symbol- (1/2+)
232Ac 232.0420 2.0 m Beta Symbol- (2-)
233Ac 2.4 m Beta Symbol- (1/2+)
234Ac 40 s Beta Symbol- (1+)
Discovered by Andre Debierne in 1899 and independently by F. Giesel in 1902. Occurs naturally in association with uranium minerals. Thirty-two isotopes and isomers are now recognized. All are radioactive. Actinium-227, a decay product of uranium-235 is an alpha and beta emitter with a 2l.77-year half- life. Its principal decay products are thorium-227 (18.72-day half-life), radium-223 (11.4-day half-life), and a number of short-lived products including radon, bismuth, polonium, and lead isotopes. In equilibrium with its decay products, it is a powerful source of alpha rays. Actinium metal has been prepared by the reduction of actinium fluoride with lithium vapor at about 1100 to 1300 °C. The chemical behavior of actinium is similar to that of the rare earths, particularly lanthanum. Purified actinium comes into equilibrium with its decay products at the end of 185 days, and then decays according to its 21.77-year half-life. It is about 150 times as active as radium, making it of value in the production of neutrons.

Actinium Decay Series (from 2U)

Actinium Decay Series


LINKS:

Actinium Decay Row
Photon Interaction Coefficients of Actinium


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Sources for the information on this website include:
Lide, David R., ed. CRC Handbook of Chemistry and Physics, 78th Ed., 1997-1998.