CAS: 7440-34-8
Description: Silvery-white radioactive metal
Classification: Actinide
Date of Discovery: 1899
Discoverer: Andre Debierne
Name Origin: Greek aktinos, "beam or ray"
Atomic Number: 89
Number of Neutrons: 138
Atomic Mass: (227) amu
Melting Point: 1051 °C
Boiling Point: 3200 ± 300 °C (est.)
Density (293 K): 10.07 g/cm3 (calc.)
Atomic volume: 22.54 cm3/mol
Electrical resistivity: Thermal conductivity: 0.12 W/cmK
Enthalpy of atomization: 301 kJ/mol (est)
Enthalpy of vaporization: Enthalpy of fusion: Specific heat capacity: 0.120 J/g/K
Energy levels: 2-8-18-32-18-9-2
Electron configuration: [Rn]6d17s2 Crystal Structure: Cubic surface centered
Atomic radius: Covalent radius: Oxidation States: +3
Electronegativity, Pauling: 1.1
Electron affinity: First ionization energy: 5.17 eV
2nd ionization energy: 12.126 eV
3rd ionization energy: Polarizability: 32.1 10-24cm3
Isotope
Natural Abundance
Atomic Mass
Half-life
Decay Mode
Spin
207Ac
0.02 s
208mAc
25 ms
208Ac
0.1 s
209Ac
209.0096
0.09 s
210Ac
210.0093
0.4 s
211Ac
211.0076
0.3 s
212Ac
212.0078
0.9 s
213Ac
213.0066
0.8 s
(9/2-)
214Ac
214.0069
8.2 s
(5+)
215Ac
215.0065
0.17 s
(9/2-)
216mAc
0.33 ms
(9-)
216Ac
216.00871
0.3 ms
(1)
217mAc
0.7 µs
217Ac
217.00933
0.07 µs
9/2-
218Ac
218.01162
1.1 µs
219Ac
219.01241
0.012 ms
(9/2-)
220Ac
220.0148
26 ms
221Ac
221.01558
52 ms
222mAc
63 s
; EC; IT
222Ac
222.01782
5 s
1-
223Ac
223.01913
2.1 m
; EC
(5/2-)
224Ac
224.021708
2.7 h
EC;
0-
225Ac
225.02322
10.0 d
3/2
226Ac
226.026089
1.224 d
EC; -;
(1-)
227Ac
227.027747
21.77 y
-;
(3/2-)
228Ac
228.031014
6.15 h
-
(3+)
229Ac
229.03293
1.04 h
-
(3/2+)
230Ac
230.0360
2.03 m
-
1+
231Ac
231.0386
7.5 m
-
(1/2+)
232Ac
232.0420
2.0 m
-
(2-)
233Ac
2.4 m
-
(1/2+)
234Ac
40 s
-
(1+)
Discovered by Andre Debierne in 1899 and independently by F. Giesel in 1902. Occurs naturally in association with uranium minerals. Thirty-two isotopes and isomers are now recognized. All are radioactive. Actinium-227, a decay product of uranium-235 is an alpha and beta emitter with a 2l.77-year half- life. Its principal decay products are thorium-227 (18.72-day half-life), radium-223 (11.4-day half-life), and a number of short-lived products including radon, bismuth, polonium, and lead isotopes. In equilibrium with its decay products, it is a powerful source of alpha rays. Actinium metal has been prepared
by the reduction of actinium fluoride with lithium vapor at about 1100 to 1300 °C. The chemical behavior of actinium is similar to that of the rare earths, particularly lanthanum. Purified actinium comes into equilibrium with its decay products at the end of 185 days, and then decays according to its 21.77-year half-life. It is about 150 times as active as radium, making it of value in the production of neutrons.