CAS: 7440-50-8
Description: Reddish-orange metal
Classification: Transition Metal
Date of Discovery: Known to the ancients
Discoverer: Unknown
Name Origin: Latin cuprum, from the island of "Cyprus"
Atomic Number: 29
Number of Neutrons: 35
Atomic Mass: 63.546(3) amu
Melting Point: 1084.62 °C
Boiling Point: 2562 °C
Density (293 K): 8.96 g/cm3 Atomic volume: 7.1 cm3/mol
Electrical resistivity: 0.596 10-6/cm Thermal conductivity: 4.01 W/cmK
Enthalpy of atomization: 338.9 kJ/mol
Enthalpy of vaporization: 300.30 kJ/mol
Enthalpy of fusion: 13.050 kJ/mol
Specific heat capacity: 0.38 J/gK
Energy levels: 2-8-17-2
Electron configuration: [Ar]3d104s1 Crystal Structure: Cubic face centered
Atomic radius: 1.57 Å
Covalent radius: 1.17 Å
Oxidation States: +1, +2
Electronegativity, Pauling: 1.9
Electron affinity: 1.235 eV
First ionization energy: 7.726 eV
2nd ionization energy: 20.292 eV
3rd ionization energy: 36.83 eV
Polarizability: 6.1 10-24cm3
Isotope
Natural Abundance
Atomic Mass
Half-life
Decay Mode
Spin
55Cu
54.9655
+
56Cu
55.9586
+
57Cu
56.94922
0.23 s
+
3/2-
58Cu
57.944541
3.21 s
+; EC
1+
59Cu
58.939504
1.36 m
+
3/2-
60Cu
59.937368
23.7 m
+; EC
2+
61Cu
60.933462
3.35 h
+
3/2-
62Cu
61.932587
9.74 m
+; EC
1+
63Cu
69.17(3)
62.929601
Stable
3/2-
64Cu
63.929768
12.701 h
-; +; EC
1+
65Cu
30.83(3)
64.927794
Stable
3/2-
66Cu
65.928873
5.09 m
-
1+
67Cu
66.92775
2.580 d
-
3/2-
68mCu
3.79 m
IT; -
6-
68Cu
67.92964
31 s
-
1+
69Cu
68.92943
2.8 m
-
3/2-
70mCu
47 s
-
5-
70Cu
69.93241
5 s
-
1+
71Cu
70.93262
20 s
-
3/2-
72Cu
71.9357
6.6 s
-
(1+)
73Cu
72.9365
3.9 s
-
74Cu
73.9401
1.6 s
-
75Cu
74.9414
1.2 s
-
76Cu
75.9455
0.64 s
-
77Cu
76.947
0.47 s
-
78Cu
77.952
0.34 s
-
79Cu
78.954
0.19 s
-
The discovery of copper dates from prehistoric times. It is said to have been mined for more than 5,000 years. It is one of man's most important metals. Copper is reddish colored, takes on a bright metallic luster, and is malleable, ductile, and a good conductor of heat and electricity (second only to silver in electrical conductivity). The electrical industry is one of the greatest users of copper. Copper occasionally occurs native, and is found in many minerals such as cuprite (Cu2O), malachite [Cu2(CO3)(OH)2], azurite [Cu3(CO3)2(OH)2] , chalcopyrite (CuFeS2), bornite (Cu5FeS4), chalcosine (Cu2S), and coveline (CuS). Large copper ore deposits are found in the U.S., Chile, Zambia, Zaire, Peru, and Canada. The most important copper ores are the sulfides, the oxides, and carbonates. From these, copper is obtained by smelting, leaching, and by electrolysis. Its alloys, brass and bronze, long used, are still very important; all American coins are now copper alloys; monel and gun metals also contain copper. The most important compunds are the oxide and the sulfate, blue vitriol; the latter has wide use as an agricultural poison and as an algicide in water purification. Copper compounds such as Fehling's solution are widely used in analytical chemistry in tests for sugar. High-purity copper (99.999+%) is available commercially. Natural copper contains two isotopes. Twenty-five other radioactive isotopes and isomers are known.
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