| Lutetium
CAS: 7439-94-3 Description: Silvery metal Classification: Rare Earth (Lanthanide) Date of Discovery: 1907 Discoverer: Georges Urbain Name Origin: Lutetia, "Paris" Alternative Name: Cassiopeium (Germany) |
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Atomic Number: 71
Number of Neutrons: 104 Atomic Mass: 174.967(1) amu Melting Point: 1663 °C Boiling Point: 3402 °C Density (25 °C): 9.8841 g/cm3 Atomic volume: 17.78 cm3/mol Electrical resistivity: 0.0185 10-6/cm 
Thermal conductivity: 0.164 W/cmK Enthalpy of atomization: 398 kJ/mol (est.) Enthalpy of vaporization: 355.90 kJ/mol Enthalpy of fusion: 18.60 kJ/mol Specific heat capacity: 0.15 J/gK |
Energy levels: 2-8-18-32-9-2
Electron configuration: [Xe]4f 145d16s2 Crystal Structure: Hexagonal Atomic radius: 2.25 Å Covalent radius: 1.56 Å Oxidation States: +3 Electronegativity, Pauling: 1.27 Electron affinity: First ionization energy: 5.43 eV 2nd ionization energy: 13.888 eV 3rd ionization energy: 20.957 eV Polarizability: 21.9 10-24cm3 |
| Isotope | Natural Abundance | Atomic Mass | Half-life | Decay Mode | Spin |
| 150Lu | 149.973 |  35 ms |
p | ||
| 151Lu | 150.967 | 0.08 s | p | ||
| 152Lu | 151.963 | 0.7 s |  - |
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| 153Lu | 152.959 | - |
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| 154Lu | 153.9571 | 1.0 s | +, EC |
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| 155mLu | 2.6 ms |  |
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| 155Lu | 154.9542 | 0.07 s | EC; |
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| 156mLu | 0.20 s | |
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| 156Lu | 155.9529 | 0.5 s |
+, EC; |
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| 157mLu | 9.6 s |
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| 157Lu | 156.95010 | 4.8 s | +, EC; |
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| 158Lu | 15794984 | 10.4 s | +, EC; |
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| 159Lu | 158.9467 | 12.3 s | +, EC |
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| 160Lu | 159.94654 | 36.1 s | +, EC |
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| 161Lu | 160.9432 | 1.2 m | +, EC |
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| 162mLu | 1.5 m |
EC | 4- | ||
| 162Lu | 161.9432 | 1.37 m | +, EC |
1- | |
| 163Lu | 162.9412 | 4.1 m | +, EC |
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| 164Lu | 163.9412 | 3.14 m | +, EC |
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| 165Lu | 164.9396 | 10.7 m | +, EC |
1/2+ | |
| 166m2Lu | 2.1 m | +; EC |
(0-) | ||
| 166m1Lu | 1.4 m | +, EC; IT |
(3-) | ||
| 166Lu | 165.9398 | 2.8 m | +; EC |
(6-) | |
| 167Lu | 166.9383 | 52 m | +; EC |
7/2+ | |
| 168mLu | 6.7 m | +; EC |
3+ | ||
| 168Lu | 167.9387 | 5.5 m | +; EC |
(6-) | |
| 169mLu | 2.7 m | IT | 1/2- | ||
| 169Lu | 168.93765 | 1.419 d | EC | 7/2+ | |
| 170mLu | 0.7 s | IT | 4- | ||
| 170Lu | 169.93847 | 2.01 d | EC | 0+ | |
| 171mLu | 1.31 m | IT | 1/2- | ||
| 171Lu | 170.937910 | 8.24 d | EC | 7/2+ | |
| 172mLu | 3.7 m | IT | 1- | ||
| 172Lu | 171.939082 | 6.70 d | EC | 4- | |
| 173Lu | 172.938927 | 1.37 y | EC | 7/2+ | |
| 174mLu | 142 d | IT; EC | 6- | ||
| 174Lu | 173.940334 | 3.3 y | EC | 1- | |
| 175Lu | 97.41(2) | 174.940768 | Stable | 7/2+ | |
| 176mLu | 3.66 h | - |
1- | ||
| 176Lu | 2.59(2) | 175.942683 | 3.8 x 1010 y | - |
7- |
| 177mLu | 160.7 d | IT; - |
23/2- | ||
| 177Lu | 176.943755 | 6.75 d | - |
7/2+ | |
| 178mLu | 23.1 m | - |
(9-) | ||
| 178Lu | 177.945952 | 28.5 m | - |
1+ | |
| 179Lu | 178.94732 | 4.6 h | - |
7/2+ | |
| 180Lu | 179.9499 | 5.7 m | - |
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| 181Lu | 180.9518 | 3.5 m | - |
(7/2+) | |
| 182Lu | 2.0 m | - |
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| 183Lu | 58 s | - |
7/2+ | ||
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In 1907, Urbain described a process by which Marignac's ytterbium (1879) could be separated into the two elements, ytterbium (neoytterbium)and lutetium. These elements were identical with "aldebaranium" and "cassiopeium," independently discovered by von Welsbach about the same time. Charles James of the University of New Hampshire also independently prepared the very pure oxide, lutecia, at this time. The spelling of
the element was changed from lutecium to lutetium in 1949. Lutetium occurs in very small amounts in nearly all minerals containing yttrium, and is present in monazite to the extent of about 0.003%, which is a commercial source. The pure metal has been isolated only in recent years and is one of the most difficult to prepare. It can be prepared by the reduction of anhydrous LuCl3 or LuF3 by an alkali or alkaline earth metal. The metal is silvery white and relatively stable in air. While new techniques, including ion-exchange reactions, have been developed to separate the various rare-earth elements, lutetium is still the most costly of all rare earths. 176Lu occurs naturally (97.41 %) with 175Lu (2.59%), which is radioactive with a very long half-life. It is radioactive with a half-life of about 4 x 1010 years. Lutetium has 49 isotopes and isomers that are now recognized. Stable lutetium nuclides, which emit pure beta radiation after thermal neutron activation, can be used as catalysts in cracking, alkylation, hydrogenation, and polymerization. Virtually no other commercial uses have been found yet for lutetium. While lutetium, like other rare-earth metals, is thought to have a low toxicity rating, it should be handled with care until more information is available.
LINKS: Information, data sheet and standard forms A lutetium product supplier Photon Interaction Coefficients of Lutetium Return
Sources for the information on this website include: Lide, David R., ed. CRC Handbook of Chemistry and Physics, 78th Ed., 1997-1998. |
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