CAS: 7440-02-0
Description: White metal
Classification: Transition Metal
Date of Discovery: 1751
Discoverer: Alex Cronstedt
Name Origin: German Nickel, "Satan" and kupfernickel, "Old Nick's copper"
Atomic Number: 28
Number of Neutrons: 31
Atomic Mass: 58.6934(2) amu
Melting Point: 1455 °C
Boiling Point: 2913 °C
Density (293 K): 8.902 g/cm3 Atomic volume: 6.59 cm3/mol
Electrical resistivity: 0.143 10-6/cm Thermal conductivity: 0.907 W/cmK
Enthalpy of atomization: 422.57 kJ/mol
Enthalpy of vaporization: 370.40 kJ/mol
Enthalpy of fusion: 17.470 kJ/mol
Specific heat capacity: 0.44 J/gK
Energy levels: 2-8-16-2
Electron configuration: [Ar]3d84s2 Crystal Structure: Cubic face centered
Atomic radius: 1.62 Å
Covalent radius: 1.15 Å
Oxidation States: 0, +1, +2,+3
Electronegativity, Pauling: 1.91
Electron affinity: 1.156 eV
First ionization energy: 7.635 eV
2nd ionization energy: 18.168 eV
3rd ionization energy: 35.17 eV
Polarizability: 6.8 10-24cm3
Isotope
Natural Abundance
Atomic Mass
Half-life
Decay Mode
Spin
51Ni
50.9877
+
52Ni
51.9757
+
53Ni
52.9685
0.05 s
+
7/2-
54Ni
53.95791
+
55Ni
54.95134
0.20 s
+
7/2-
56Ni
55.94214
6.08 d
EC
0+
57Ni
56.939800
35.6 h
+; EC
3/2-
58Ni
68.077(9)
57.935348
Stable
0+
59Ni
58.934351
7.6 x 104 y
EC
3/2-
60Ni
26.223(8)
59.930790
Stable
0+
61Ni
1.140(1)
60.931060
Stable
3/2-
62Ni
3.634(2)
61.928348
Stable
0+
63Ni
62.929673
100. y
-
1/2-
64Ni
0.926(1)
63.927969
Stable
0+
65Ni
64.930088
2.517 h
-
5/2-
66Ni
65.92912
54.6 h
-
0+
67Ni
66.93157
21 s
-
1/2-
68Ni
67.93185
19 s
-
69Ni
68.9352
10 s
-
70Ni
69.9361
-
71Ni
70.9400
1.9 s
-
72Ni
71.9413
2.1 s
-
73Ni
72.946
0.9 s
-
74Ni
73.948
1.1 s
-
Discovered by Cronstedt in 1751 in kupfernickel (niccolite). Nickel is found as a
constitutent in most meterorites and often serves as one of the criteria for
distinguishing a meteorite from other minerals. Iron meteorites, or siderites, may
contain iron alloyed with from 5 to nearly 20% nickel. Nickel is obtained
commercially from pentlandite [(Ni,Fe)9S8] and pyrrhotite of the Sudbury region of Ontario, a district that produces much of the world's nickel. Other deposits are found in New Caledonia, Australia, Cuba, Indonesia, and elsewhere. Nickel is silvery white and takes on a high polish. It is hard, malleable, ductile, somewhat ferromagnetic, and a fair conductor of heat and electricity. It belongs to the iron-cobalt group of metals and is chiefly valuable for the alloys it forms. It is extensively used for making stainless steel and other corrrosion-resistant alloys such
as Invar®, Monel®, Inconel®, and the Hastelloys®. Tubing made of
copper-nickel alloy is extensively used in making desalination plants for converting
sea water into fresh water. Nickel is also now used extensively in coinage and in
making nickel steel for armor plate and burglar-proof vaults, and is a component in
Nichrome®, Permalloy®, and constantan. Nickel added to glass gives a green
color. Nickel plating is often used to provide a protective coating for other metals,
and finely divided nickel is a catalyst for hydrogenating vegetable oils. It is also used in ceramics, in the manufacture of Alnico magnets, and in the Edison® storage
battery. The sulfate and the oxides are important compounds. Natural nickel is a
mixture of five stable isotopes; nineteen other unstable isotopes are known. Nickel sulfide fume and dust is recognized as having carcinogenic potential.
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