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Nickel - Ni

CAS: 7440-02-0
Description: White metal
Classification: Transition Metal
Date of Discovery: 1751
Discoverer: Alex Cronstedt
Name Origin: German Nickel, "Satan" and kupfernickel, "Old Nick's copper"

Atomic Number: 28
Number of Neutrons: 31
Atomic Mass: 58.6934(2) amu
Melting Point: 1455 °C
Boiling Point: 2913 °C
Density (293 K): 8.902 g/cm3
Atomic volume: 6.59 cm3/mol
Electrical resistivity: 0.143 10-6/cm Ohm Symbol
Thermal conductivity: 0.907 W/cmK
Enthalpy of atomization: 422.57 kJ/mol
Enthalpy of vaporization: 370.40 kJ/mol
Enthalpy of fusion: 17.470 kJ/mol
Specific heat capacity: 0.44 J/gK
Energy levels: 2-8-16-2
Electron configuration: [Ar]3d84s2
Crystal Structure: Cubic face centered
Atomic radius: 1.62 Å
Covalent radius: 1.15 Å
Oxidation States: 0, +1, +2,+3
Electronegativity, Pauling: 1.91
Electron affinity: 1.156 eV
First ionization energy: 7.635 eV
2nd ionization energy: 18.168 eV
3rd ionization energy: 35.17 eV
Polarizability: 6.8 10-24cm3
Isotope Natural Abundance Atomic Mass Half-life Decay Mode Spin
51Ni 50.9877 Beta Symbol+
52Ni 51.9757 Beta Symbol+
53Ni 52.9685 0.05 s Beta Symbol+ 7/2-
54Ni 53.95791 Beta Symbol+
55Ni 54.95134 0.20 s Beta Symbol+ 7/2-
56Ni 55.94214 6.08 d EC 0+
57Ni 56.939800 35.6 h Beta Symbol+; EC 3/2-
58Ni 68.077(9) 57.935348 Stable 0+
59Ni 58.934351 Alpha Symbol7.6 x 104 y EC 3/2-
60Ni 26.223(8) 59.930790 Stable 0+
61Ni 1.140(1) 60.931060 Stable 3/2-
62Ni 3.634(2) 61.928348 Stable 0+
63Ni 62.929673 100. y Beta Symbol- 1/2-
64Ni 0.926(1) 63.927969 Stable 0+
65Ni 64.930088 2.517 h Beta Symbol- 5/2-
66Ni 65.92912 54.6 h Beta Symbol- 0+
67Ni 66.93157 21 s Beta Symbol- 1/2-
68Ni 67.93185 19 s Beta Symbol-
69Ni 68.9352 10 s Beta Symbol-
70Ni 69.9361 Beta Symbol-
71Ni 70.9400 1.9 s Beta Symbol-
72Ni 71.9413 2.1 s Beta Symbol-
73Ni 72.946 0.9 s Beta Symbol-
74Ni 73.948 1.1 s Beta Symbol-
Discovered by Cronstedt in 1751 in kupfernickel (niccolite). Nickel is found as a constitutent in most meterorites and often serves as one of the criteria for distinguishing a meteorite from other minerals. Iron meteorites, or siderites, may contain iron alloyed with from 5 to nearly 20% nickel. Nickel is obtained commercially from pentlandite [(Ni,Fe)9S8] and pyrrhotite of the Sudbury region of Ontario, a district that produces much of the world's nickel. Other deposits are found in New Caledonia, Australia, Cuba, Indonesia, and elsewhere. Nickel is silvery white and takes on a high polish. It is hard, malleable, ductile, somewhat ferromagnetic, and a fair conductor of heat and electricity. It belongs to the iron-cobalt group of metals and is chiefly valuable for the alloys it forms. It is extensively used for making stainless steel and other corrrosion-resistant alloys such as Invar®, Monel®, Inconel®, and the Hastelloys®. Tubing made of copper-nickel alloy is extensively used in making desalination plants for converting sea water into fresh water. Nickel is also now used extensively in coinage and in making nickel steel for armor plate and burglar-proof vaults, and is a component in Nichrome®, Permalloy®, and constantan. Nickel added to glass gives a green color. Nickel plating is often used to provide a protective coating for other metals, and finely divided nickel is a catalyst for hydrogenating vegetable oils. It is also used in ceramics, in the manufacture of Alnico magnets, and in the Edison® storage battery. The sulfate and the oxides are important compounds. Natural nickel is a mixture of five stable isotopes; nineteen other unstable isotopes are known. Nickel sulfide fume and dust is recognized as having carcinogenic potential.
LINKS:

Marine Appplications of Copper-Nickle Alloys
Nickel allergy
Nickel Development Institute
Nickel exposure
Nickel Hydride batteries
The Nickel Page
On Nickel
Recycling Nickel-Cadmium Batteries


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Sources for the information on this website include:
Lide, David R., ed. CRC Handbook of Chemistry and Physics, 78th Ed., 1997-1998.